I research my family tree for 15 years before taking a DNA test.
My whole Paternal side was wrong, Dad was not my Biological Father.
I now know who my Biological Father is and I now have a brand new pair of Siblings and all their family as blood relatives.
So yes, DNA will give you more family to include in your family tree.
But there can be skeletons unearthed so be prepared.
The thing is one DNA test is not really enough, ideally at least one First Cousin on each side should also test. Then you can cross reference and validate ancestors by linking other DNA Cousins back to the MRCA (most recent common ancestors).
Finally, if you do proceed then do not be lulled into buying the cheapest, only buy from Ancestry as once you have worked through your DNA matches of note you can copy and upload the results of the test to other sites, but you cannot upload to Ancestry. Plus Ancestry has by far the biggest number of DNA testers.