Hi Daveo,
Welcome to rootschat

I don't suppose you have the 1861 census? There is another son:
Rg9/1988
Folio 81 p. 6
Wolverhampton, Staffordshire
29 Bloomsbury Street
George White, head, 43, Japanner journeyman, b. Wolverhampton
Charlotte, wife, 29, b. Salop Cleobury
George, son, 12, Castor (?), b. Wolverhampton
Alfred, son, 5, scholar, b. Wolverhampton
James, son, 4, scholar, b. Wolverhampton
William, son, 1, b. Wolverhampton
This doesn't solve your marriage problem, of course.
Tanja