Good morning Sue. I am pretty convinced the young women with the child is Phoebe Pullen with her baby son Mark, and the others I think are her uncle, Cinnementy's brother, Samuel Smith, and her two brothers Peter and Charles Hearn. I am basing that on the 1901 census which must have been taken about seven to eight months later:
John Hearne Head M 49 Watford, Hertfordshire
Sinamenty Hearne Wife F 47 Watford, Hertfordshire
Mershach Hearne Son M 16 Fulham, London
Peter Hearne Son M 24 Fulham, London
Charles Hearne Son M 13 Fulham, London
Phoebe Pullin Daughter F 21 Watford, Hertfordshire
Samuel Smith Brother-In-Law M 52 Chiswick, Middlesex
John Le Aby Nephew M 21 Fulham, London
Mark Pullin Grand Son M 1 Uxbridge, Middlesex
Of course it is possible the man I have guessed as being Peter Hearn, 24, might be Phoebe's husband instead. It is a shame there are no other photos to compare with.
Best regards
Richard