I'm going purely off of what I have heard from my mother...they were both Catholics, on the census too....but they were for some reason married in a Church of Ireland Church in Dublin...the children were raised in that faith as far as I know, with classic Irish Catholic names...they were all born and raised in County Wicklow
When was the marriage and when were the births?
Both civil laws and religious requirements regarding marriage were a bit confusing in Ireland in 19th & early 20th century and they changed during that period. That's why we can't try to answer your questions with confidence unless we know when events occurred.
Have you considered that your great grandparents may have had a later wedding ceremony in a Catholic church?
Added. Which census? Was it when they were a married couple? How long did they say they had been married?