Hi Scotty,
I've now located Ann's siblings:-
Elizabeth PIPPEY bap 4th October 1818 at St James, Bristol. (Reg 2b, Page 82, No.656)
Frances PIPPEY bap 2nd September 1821 at St Paul, Bristol. (Reg 1b, Page 123, No. 982)
John PIPPEY bap 2nd October 1825 at St James, Bristol. (Reg 2c, Page 247, No.1975)
Victor