Hi,
Thanks for your replies. I forgot to mention that I had found him on the census - those above are the ones that I've found.
1871 - he's a widow
1881 - he's a widow, living with parents, daughter Bessie, niece and nephew. Frederick A (ubrey) Waight is also living with them - not sure of the connection, but he's also mentioned in will
1891 - he's a widow, living with servant and lodger Stephen Gillham (mentioned in will - Charles wanted funeral to same standard as his)
1901 - he's mentioned as a widow, living with Walter Goodall (boarder), Lydia Pamplin (servant), Amy Ethel Pamplin (servant) and James Davis (Pamplin) a 3 month baby
1911 - he's still living with Walter Goodall, Lydia Pamplin and James (davis) Pamplin - now adopted son, and Walter Goodall Pamplin (now adopted son).
I assume that his second marriage is sometime between the censuses, but I can't seem to find anything that fits in any of the marriage records...