Princess Alexandra, later Queen was married to Edward VII they never lived at Kew.
"The exotic garden at Kew Park, formed by Lord Capel John of Tewkesbury, was enlarged and extended by Augusta, Dowager Princess of Wales, the widow of Frederick, Prince of Wales. The origins of Kew Gardens can be traced to the merging of the royal estates of Richmond and Kew in 1772. William Chambers built several garden structures, including the lofty Chinese pagoda built in 1761 which still remains. George III enriched the gardens, aided by William Aiton and Sir Joseph Banks. The old Kew Park (by then renamed the White House), was demolished in 1802. The "Dutch House" adjoining was purchased by George III in 1781 as a nursery for the royal children. It is a plain brick structure now known as Kew Palace."