... straw bonnet maker ...
Here's "Mrs. H. DODD" (most likely to be Bethany) in another Directory listing.
1870-71 (Wise's)
DODD - Mrs H.
Milliner and Draper
George Street, Dunedin,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
There were some other listings under "Henry DODD" (suspect this is Herman Henry? ) also ...
1878 & 1880
DODD - Henry
Leasehold : George Street - shop and dwelling,,,,,,,,,,,,,,,,,,
1887 & 1890
DODD - Henry
Settler
Residential: Scotland Street ,,,,,,,,,,,,,,,,,,
and this one back in
1861DODD - Henry
Electoral claim
"Otago Colonist" (newspaper ?) - 12 April 1861

,,,,,,,,,,,,,,,,,,
Possibly 1861 Henry (is Herman Henry) ?
Have also just noticed a birth registered in 1862 for a "Catherine DODD".

[Parents names not on index and can't tell, where this birth was registered. ] So maybe the DODDs did arrive around this time ?