Hello Mrs.G
The lady is wearing a style favoured by older women from 1870's well into the 90's.
The man's style of jacket also 1870's into the 1880's.
The youngest lad's Norfolk jacket & Eton collar are more associated with the 1880's to around 1920 but his military style cap was a trend for boys in the 1870's.
There's something odd about this that you may not have noticed & that is,this photo is in reverse.The lady's wedding ring appears on her right hand & the man's jacket & waistcoat are buttoned the wrong side.
This originally was a Tintype,which was a thin sheet of iron which was put in the camera & the image was burned directly onto it,creating a mirror image.As you can see this is on card which means this is a copy of the original 1870's Tintype.
If this had been anything other than a Tintype I would have said 1880's.
This is what they would have looked like at the sitting.
jim