FreeBMD has a marriage in Sep qtr 1891, Paddington, for a Charles LUMLEY, where one of the brides is an Elizabeth MATTHEWS. This could be the one.
In 1891 Charles is a boarder in the household of John BALDWIN in Paddington, so the marriage is quite likely to be the right one. He was single 25, a Railway Porter, and born Wales, Anglesea.
1901
7 Hasbro St, Paddington
Charles LUMLEY, head mar 35, Foreman porter GWR, born Anglesea, N Wales
Maria E LUMLEY, wife mar 32, born Brochley, Worc
Charles B LUMLEY, son 9, born London, Paddington
Robert T LUMLEY, son 5, born ditto
George PETERS, boarder 14, Van boy GWR, born Blaydon, Devon
RG13/2/84/35
Ian C