Thank you Kerry.
Unfortunately I only know that his father was Thomas Smith, farmer,
and that Charles, bachelor,aged 27 married Eliza, spinster, aged 28, by Vicar General's Licence (Records at Lambeth Palace Library) on 23 Feb 1857 which puts Charles birth at 1830.
The Whitehead family originated from Baxterley, N. Warwicks, and there is om tje Return of owners of Land 1871 mention of a Thomas Smith of Baxterley, farmer of 726 acres. However I still have not found Charles in any Census.
In 1861 Census Eliza is listed (married (sic) and living with her father Joseph, now retired in Corley. This couple are the most elusive of all my paternal line which goes back to 1600s in Warwickshire. Sorry no more info on Charles.