Only the first marriage of William Williams was in Maker CON although it is unlikely he lived there for any period of time:
William Williams, bachelor, minor, sojourner, of this parish, married Lydia Malachi, spinster, sojourner, of this parish by banns on 19 May 1829. Married by Thomas Hunt Ley, Curate. The groom made his mark while the bride signed her name as Lydia Malachy. The witnesses were James
Williams and H Hambly. (Ref P134/1/8 No 769, page 257.
I have the following transcriptions of census returns:
1841 Census of dis. 17 Calstock CON taken on 6 Jun 1841
William WILLIAMS, M, age 35, miner of lead silver, b. CON
Louisa WILLIAMS, F, age 24, b. CON
Susan WILLIAMS, F, age 10, b. CON
Lydia WILLIAMS, F, age 8, b. CON
William WILLIAMS, M, age 4, b. CON
James WILLIAMS, M, age 2, b. CON
Caroline WILLIAMS, F, age 1 ano, b. CON
Christiane MOON, F, age 45, b. CON
Nicholas MOON, M, age 20, b. CON
1851 Census of St Andrew, Plymouth DEV taken on 30 Mar 1851
William WILLIAMS, head, mar, M, age 49, miner of copper, b. Calstock
Louisa WILLIAMS, wife, mar, F, age 34, b. Calstock
William WILLIAMS, son, unmar, M, age 13, scholar, b. Calstock
James WILLIAMS, son, unmar, M, age 12, scholar, b. Calstock
Caroline WILLIAMS, dau, unmar, F, age 11, scholar, b. Calstock
Louisa WILLIAMS, dau, unmar, F, age 5, scholar, b. Calstock
Charles WILLIAMS, son, unmar, M, age 1, b. Plymouth Devon
Christian MOON, suegra, wid, F, age 54, b. St Anne CON
Richard MOON, cuñado, unmar, M, age 32, shoemaker, b. Calstock
1861 Census of dis. 15 Calstock CON taken on 7 Apr 1861
Louisa WILLIAMS, wife, mar, F, age 44, wife of miner, b. Calstock
William H. WILLIAMS, son, unmar, M, age 23, motor man in mines, b. Calstock
James WILLIAMS, son, unmar, M, age 22, miner of copper, b. Calstock
Caroline WILLIAMS, dau, unmar, F, age 21, b. Calstock
Louisa E. WILLIAMS, dau, unmar, F, age 15, b. Calstock
Charles J. WILLIAMS, son, unmar, M, age 12, scholar, b. Plymouth Devon
Alfred WILLIAMS, son, unmar, M, age 6, b. Calstock
Theodore A. WILLIAMS, son, unmar, M, age 4, b. Calstock
Minnie L. WILLIAMS, niece, unmar, F, age 1 ano, b. Calstock
1871 Census of dis. 14 Calstock CON taken on 2 Apr 1871
William WILLIAMS, head, mar, M, age 68, miner of tin, b. Calstock
Louise WILLIAMS, wife, mar, F, age 54, b. Calstock
Louise WILLIAMS, dau, unmar, F, age 25, straw hat maker, b. Calstock
John WILLIAMS, son, unmar, M, age 22, miner of tin, b. Calstock
Alfred WILLIAMS, son, unmar, M, age 16, shoemaker, b. Calstock
Albert WILLIAMS, son, -, M, age 14, b. Calstock
Births
Mar 1866 Emily WILLIAMS Tavistock vol. 5b page 403
Mar 1873 Minnie Louisa WILLIAMS Tavistock vol. 5b page 376
Jun 1877 James William WILLIAMS Tavistock vol. 5b page 371
Baptisms
William Henry WILLIAMS chr 21 May 1837 in Calstock, s/o William (miner) & Louisa of Calstock
James WILLIAMS chr 21 Oct 1838 in Calstock, s/o William (miner) & Louisa of Harrowbare
Caroline WILLIAMS chr 16 Feb 1840 in Calstock, d/o William (miner) & Louisa of Harrowborough
Charles WILLIAMS chr 9 Jan 1842 in Calstock, s/o William (miner) & Louisa of Harrowbarrow
Theodore Albert WILLIAMS chr Jan 1858 in Calstock, s/o William (miner) y Louisa of Gunnislake born 14 Nov 1856
Marriages
Sep 1864 James WILLIAMS m. Mary Louisa STILE in Stoke Damerel vol. 5b page 548
James WILLIAMS m. Mary Louisa STILE on 14 Jul 1864 in Stoke Damerel, DEV (ent 47 in Register)
Deaths
Sep 1873 William WILLIAMS aged 70 Tavistock vol. 5b page 213
Mar 1878 James William WILLIAMS, aged 0, Tavistock 5b 311
Sep 1880 Louisa WILLIAMS aged 64, Tavistock vol. 5b page 251
Burials
William WILLIAMS, aged 70, buried on 16 Jul 1873 in Calstock CON
Louisa WILLIAMS, aged 64, buried on 24 Sep 1880 in Calstock CON
I cannot say if these Williams are related to yours. Calstock was once unofficially called Williamstown as a Williams bought several mines and employed family to mine them.