Charlie
I do think you need the details of Caroline Sarah Grace Catling's marriage.
1. This marriage needs to prove Caroline was the daughter of John Frederick Catling (if the marriage isn't sufficient then you will need her birth certificate as well - luckily her combination of names means there can be no confusion that the 1860 birth reference and the 1880 marriage reference are the same Caroline)
2. The marriage also needs to prove this is the right Caroline Ward the same one living at the 1891 census address given on Charles' army papers.
However you do have Charles' other potential sibling John William Viner Catling at the same address '17 Dunn Street Hackney' on the 1891 census so even without the final proof of Caroline Sarah Grace's marriage details it feels very much like a 'done deal' as far as Catling to Ringrose for your Charles is concerned.
Once you've proved Caroline Sarah Grace Ward nee Catling was the sister of Charles Ringrose/Charles Christian H. Catling, to your satisfaction, (and you've been kept busy finding what ultimately happened to John Frederick and his wife Eliza Mary nee Ringrose) this might be Eliza Mary on the 1851 census (her marriage details will obviously help).
1851 census HO107 1711 folio 380
Hertingfordbury Road Hertford St Andrew Hertfordshire
John Ringrose 60 Bugden, Huntingdonshire, Head Married Tailor
Caroline Ringrose 62 Bristol, Somerset, Wife Married
Hannah Ringrose 39 Little Amwell, Hertfordshire, Daughter Married
Eliza Ringrose 12 Hertford, Hertfordshire, Daughter
William F Ringrose 10 Hertford, Hertfordshire, Grandson
and possibly the same family
1861 census RG9 247 folio 15
15 York Street Shoreditch St Leonard Middlesex
William Ringrose 43 Hertford, Hertfordshire, Head Married Tailor
Hannah Ringrose 48 Hertford, Hertfordshire, Wife
William Ringrose 20?(30) Shoreditch, Middlesex, Son Tailor
Charles Ringrose 4 Shoreditch, Middlesex, Son
1871 census RG10 466 folio 31
2 Labernam Terrace St Leonard Shoreditch London
William Ringrose 54 Hertfordshire, Head Married Tailor
Susan Ringrose 57 Hertfordshire, Wife Married
Charles Ringrose 15 London, Middlesex, Son Unmarried Butcher
On the 1881 census William's wife's name is Susannah.
but
1841 census HO107 707/5 folio 23 page 7
Allerton Street St Leonard Shoreditch Middlesex
William Ringrose 20 Middlesex Tailor
Hannah Ringrose 24 Middlesex
Mary Ringrose 16 Middlesex
William Ringrose 4 Middlesex
(perhaps on this census the children's ages were mistakenly given in months not years? - still doesn't quite work as Mary Eliza was older than 16 months on the June 1841 census)
MARY ELIZA RINGROSE
Christening: 24 FEB 1839 Saint Andrews, Hertford, Hertford
Father: WILLIAM RINGROSE
Mother: HANNAH
Births Mar 1839
Ringrose Mary Eliza Hertford 6 480
Marriages Mar 1839
RINGROSE William Ware 6 645
DEARDS Hannah Ware 6 645
WILLIAM RINGROSE
HANNAH DEARDS
Marriage: 06 JAN 1839 Great Amwell, Hertford
Births Mar 1841
RINGROSE William Frederic[hk] Shoreditch 2 389
WILLIAM FREDERICK RINGROSE
Birth: 15 FEB 1841
Christening: 30 JAN 1842 Saint John The Baptist, Shoreditch, London
Father: WILLIAM RINGROSE
Mother: SUSANNAH
so plenty to work out further with Ringroses.
Catlings seem less confusing
JOHN FREDERICK CATLING
Birth: 28 NOV 1836
Christening: 09 JAN 1837 Saint Leonards, Shoreditch, London,
Father: JOHN CATLING
Mother: SARAH
Siblings- full IGI entries will give birth dates
SARAH ELIZABETH CATLIN Christening: 24 JUN 1838 Saint Leonards, Shoreditch, London
SARAH ELIZABETH CATLING Christening: 18 OCT 1841 Saint Leonards, Shoreditch, London
WILLIAM HENRY CATLING Christening: 15 APR 1844 Saint Leonards, Shoreditch, London
EDWARD WILLIAM CATLING
Birth: 11 DEC 1833
Christening: 24 AUG 1834 Saint Andrew, Holborn, London
Father: JOHN CATLING
Mother: SARAH
1841 census HO107 705/3 folio 6 page 25
Nottingham Place St Leonard Shoreditch Middlesex
John Catling 45 Middlesex Book maker
Sarah Catling 36 Middlesex
Edward Catling 7 Middlesex
John Catling 5 Middlesex
1851 census HO107 1537 folio 298
2 Nottingham Place Shoreditch Middlesex
John Catling 55 St Giles, Middlesex, Head Married Backmaker?
Sarah Catling 46 St Giles, Middlesex, Wife Married
Edward Wm Catling 17 St Luke, Middlesex, Son Errand Boy
Jn Fredrick Catling 15 St Luke, Middlesex, Son Errand Boy
Sarh Elizabeth Catling 9 Shoreditch, Middlesex, Daughter
Wm Henry Catling 7 Shoreditch, Middlesex, Son
Thomas Vince Catling 2 Shoreditch, Middlesex, Son
1861 census RG9 247 folio 48
15 Labernam Terrace Shoreditch Middlesex
Sarah G Catling 58 St Giles, Middlesex, Head Widow Charwoman or Chain woman?
Sarah Elizth Catling 20 Shoreditch, Middlesex, Daughter milliner
William Henry Catling 17 Shoreditch, Middlesex, Son Office Boy
Thomas Vince Catling 13 Shoreditch, Middlesex, Servant Errand Boy
Regards
Valda